全文获取类型
收费全文 | 1071篇 |
免费 | 96篇 |
国内免费 | 170篇 |
专业分类
安全科学 | 50篇 |
废物处理 | 31篇 |
环保管理 | 72篇 |
综合类 | 439篇 |
基础理论 | 165篇 |
污染及防治 | 235篇 |
评价与监测 | 301篇 |
社会与环境 | 35篇 |
灾害及防治 | 9篇 |
出版年
2024年 | 8篇 |
2023年 | 19篇 |
2022年 | 38篇 |
2021年 | 38篇 |
2020年 | 38篇 |
2019年 | 28篇 |
2018年 | 27篇 |
2017年 | 44篇 |
2016年 | 53篇 |
2015年 | 55篇 |
2014年 | 76篇 |
2013年 | 143篇 |
2012年 | 94篇 |
2011年 | 120篇 |
2010年 | 65篇 |
2009年 | 87篇 |
2008年 | 54篇 |
2007年 | 67篇 |
2006年 | 36篇 |
2005年 | 38篇 |
2004年 | 23篇 |
2003年 | 28篇 |
2002年 | 19篇 |
2001年 | 17篇 |
2000年 | 18篇 |
1999年 | 12篇 |
1998年 | 17篇 |
1997年 | 12篇 |
1996年 | 8篇 |
1995年 | 15篇 |
1994年 | 12篇 |
1993年 | 10篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1972年 | 1篇 |
1970年 | 1篇 |
1968年 | 1篇 |
排序方式: 共有1337条查询结果,搜索用时 265 毫秒
31.
This paper introduces graphical strategies for the design of an evaporation/crystallization network for ternary wastewater environmental applications. Sources, sinks and other streams are located on a ternary composition diagram. While a source is any wastewater stream that has the potential to be recycled, a sink is any unit in the process that can accept sources. The proposed methodology is extremely simple to understand and implement, as it only requires basic solid-liquid phase equilibria data and uses lever arm principles to generate alternative process designs. Geometric constructions are carried out on the ternary composition diagram and the respective lever arms are used to determine intermediate flow rates in the evaporation/crystallization network. The relative locations and flow rates of the sources and sinks under consideration, as well as the unique shape of the solid-liquid equilibrium, drive the design of the separation (via evaporation/crystallization) network. Some generic structures are proposed for a typical evaporation and crystallization network. Once the general problem statement has been defined, special cases consisting of a single source-single sink, single source-two sinks and two sources-single sink are described. These special cases are representative of commonly occurring industrial wastewater design problems. Several graphical insights are listed that allow one to represent evaporation and crystallization operations on a ternary triangular composition diagram and avoid mathematical complexity. The possibility of bypassing a part of the initial feed streams is also considered. Certain feasible composition regions are identified on the ternary composition diagram for cases dealing with multiple sources and sinks. The methodology is useful in pre-screening and eliminating certain sources/sinks and is readily applicable to cases with lower number of sources and sinks. A case study involving the ammonium nitrate manufacturing process is included to demonstrate the broad applicability and value of the proposed approach. 相似文献
32.
悬浮液进样原子荧光光谱法测定海洋沉积物样品中的痕量汞 总被引:2,自引:1,他引:2
研究了一种使用悬浮液进样原子荧光光谱法测定海洋沉积初中痕量汞的快速简便的方法。控制悬浮液的颗粒粒径在200目(d≤0.076mm),用磁力搅拌器搅拌以保证悬浮液分散均匀稳定,以水溶液标准作标准曲线,该法方法的检出限为0.001μg/L,加标回收率为90.5%-103.4%,RSD为4.39%。将此法用于标准物质GBw07314、GBw08301、GSBZ50013—88、GSB50014—88和实验室外控样的分析,得到了满意的结果,证明该方法准确可靠。 相似文献
33.
通过进样管道的设计,可能存在的干扰,以及工作参数的详细研究,建立了用冷原子吸收光度法直接测定工业用浓盐酸中痕量汞的分析方法。实际样品测定结果表明,该方法可靠,准确可行。 相似文献
34.
应用自动化前处理设备和气相色谱串联四级杆质谱仪建立了淡水鱼体中10种有机磷阻燃剂的检测方法。该方法先采用自动索氏提取仪进行样品的提取,再应用凝胶渗透色谱净化仪和florisil柱对提取液进行两级净化,最后用气相色谱串联四级杆质谱法(多反应监测模式)对样品中的有机磷阻燃剂(OPFRs)定性定量。实验表明,凝胶渗透色谱净化系统在以乙酸乙酯∶环己烷(1∶1,V/V)为流动相,流速为5.0 m L·min-1的条件下,收集OPFRs的最佳时间为900~1 680 s;方法的检出限为0.002~0.192 ng·g~(-1)湿重,加标水平为5.000 ng·g~(-1)湿重时,平均加标回收率为48.7%~122%,相对偏差除磷酸三乙酯(TEP)(17.7%)和磷酸三(1,3-二氯异丙基)酯(TDCP)(11.9%)外均小于10%。应用该方法测定采集于东江某污水处理厂入河排污口的鱼类样品时,回收率指示物(d27-TBP)的回收率为82.4%~114%,鱼类样品中∑OPFRs的浓度范围为nd~6.41 ng·g~(-1)湿重。 相似文献
35.
Anna Stachniuk Agnieszka Szmagara Renata Czeczko Emilia Fornal 《Journal of environmental science and health. Part. B》2017,52(7):446-457
The aim of the research is to evaluate pesticide residue contamination of fresh and frozen fruits and vegetables, agricultural raw material, purchased from Polish farmers for production of frozen fruits and vegetables, and the estimation of the multiresidue method effectiveness expressed as the proportion of pesticides detected in food samples to the total number of pesticides analyzed by multiresidue methods. A total of 144 samples (of black currants, red currants, raspberries, cherries, strawberries, blackberries, cauliflowers and broccoli) were analyzed using LC-MS/MS method for the determination of 60 pesticides. QuEChERS extraction, matrix-matched calibration and dynamic multiple reaction monitoring method were used. Residues of 15 compounds, mainly fungicides and insecticides, were detected in 46 samples. The percentage of samples with residues above the maximum residue levels (MRL) was 15%, whereas samples with residues below MRL were 17%. A total of 13 samples contained more than one pesticide residue. Pesticide residues were detected most often in samples of black currants (50%), broccoli (36.4%), raspberries (29%) and red currants (21.8%). The most frequently detected pesticides were carbendazim and acetamiprid. The proportion of pesticides detected during our study to the total number of analyzed pesticides amounted to 25%. It was compared to literature findings. For three fourth of multiresidue methods, the proportion was below 50% for methods developed for the analysis of less than 100 pesticides, and below 30% for methods developed for the analysis of more than 100 pesticides. It appears that a lot of efforts and means is lost on pesticides never or rarely detected in examined samples. The workload and cost effectiveness of the development and application of multiresidue methods along with the range of pesticides covered by the method should be carefully and thoroughly considered anytime when a new method or workflow is developed. Including non-targeted screenings in pesticide residue control seems to be an alternative worth considering. 相似文献
36.
The subsea wellhead connector is a critical connection component between subsea Christmas tree and subsea wellhead for preventing the leakage of oil and gas in the subsea production system. Excited by cyclical loadings due to environmental forces and the other support forces, the subsea wellhead connector is prone to the failure, which could lead to the loss of subsea tree or wellhead integrity and even catastrophic accidents. With the Monte Carlo simulation method, this paper presents a reliability analysis approach based on dynamic Bayesian Networks, aiming to assess the failure probability of the subsea wellhead connector during service life. Take the driving ring component of the subsea wellhead connector as an example to demonstrate the reasonability of the proposed model. The generation data is processed by the transform between the numerical value and the state variable. Based on the stress-strength interference theory, the structure reliability of the driving ring with 96.26% is achieved by the proposed model with the consideration the aging of the material strength and the most influential factors are figured out. Meanwhile, the corresponding control measures are proposed effectively reduce the failure risk of the subsea wellhead connector during service life. 相似文献
37.
Hamide Elvan Bayrak Mehmet Tufekci Hacer Bayrak Celal Duran Mustafa Soylak 《毒物与环境化学》2017,99(4):590-600
A simple and sensitive solid phase extraction method was developed for simultaneous separation and preconcentration of gold and palladium ions with N-(4-methylphenyl)-2-{[(4-phenyl-5-pyridine-4-yl-4H-1,2,4-triazol-3-yl)thio]acetyl}hydrazine carbo thioamide complex on Amberlite XAD-1180 resin before their determination by flame atomic absorption spectrometry. Some analytical parameters such as HNO3 concentration of the sample solution, amount of complexing agent, sample volume, eluent type and volume, effects of foreign ions and adsorption capacity of the resin were investigated for quantitative recovery of gold and palladium ions. The effects of some anions and cations were also examined. Under optimum conditions, the detection limits for gold and palladium ions were found to be 0.29 and 0.19 μg L?1, respectively. The preconcentration factor for gold and palladium was 250. After being validated by standard addition and analysis of standard reference material, the procedure was successfully applied to the analysis of sea and stream water, anodic slime, gold ore, soil and electronic waste. 相似文献
38.
采用石墨炉原子吸收法测定水中铊,对样品前处理的多个细节进行改进,使前处理过程耗时缩短,回收率提高。试验表明,方法在0μg/L ~50.0μg/L范围内线性良好,相关系数r为0.9995;检出限为2.0μg/L,取样量为500 mL,富集50倍时,方法检出限为0.04μg/L;实际水样测定结果的 RSD 为4.9%~8.4%;实际样品的加标回收率为94.0%~102%。 相似文献
39.
结合爆破振动的作用机理,分别对减少振源爆炸能量、干扰降振、阻断振动波传播途径、控制爆破规模、合理选择分段间隔时间等爆破振动主要控制措施进行了分析讨论。并根据实际施工情况分析了通过电子雷管实现干扰降振的减振效果,为类似工程提供借鉴作用。 相似文献
40.
Evaluating potential hazards caused by accidental LNG release from underwater pipelines or vessels is a significant consideration in marine transportation safety. The aim of this study was to capture the dynamic behavior of LNG jet released under water and to analyze its vapor dispersion characteristics and combustion characteristics on the water surface during different release scenarios. Controlled experiments were conducted where LNG was jet released from a cryogenic storage tank. The dynamic process of LNG being jet released from orifices of different sizes and shapes, as well as the rising plume structure, were captured by a high-speed camera. The leakage flow rate and pipeline pressure were recorded by a flow meter and pressure gauge, respectively. The concentration distribution that emanated from the water surface was measured utilizing methane sensors in different positions with various wind speeds. The flame combustion characteristics of LNG vapor clouds, which immediately ignited upon the enclosed water tank, were also recorded. Additionally, the mass burning rate of the flame on the water surface was evaluated, and a new correlation between the ratio of flame length and width was established. The results indicated a large dimensionless heat release rate (Q*) and a continuous release flow rate in a limited burning area. This study could provide greater understanding of the mechanisms of LNG release and combustion behavior under water. 相似文献